1H-Benzimidazole-2(3H)-thione

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1H-Benzimidazole-2(3H)-thione

The asymmetric unit of the title compound, C(7)H(6)N(2)S, contains one half-mol-ecule; the C and S atoms of the C=S group lie on a crystallographic mirror plane. In the crystal structure, inter-molecular N-H⋯S hydrogen bonds link the mol-ecules.

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1-Methyl-1H-benzimidazole-2(3H)-thione

The title compound, C(8)H(8)N(2)S, was prepared by the condensation of N-methyl-1,2-phenyl-enediamine and carbon disulfide. The crystal structure is stabilized by a C-H⋯π inter-action between a benzene H atom and the benzene ring of a neighbouring mol-ecule, and by inter-molecular N-H⋯S inter-actions.

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1,3-Bis(ethoxy­meth­yl)-1H-benzimidazole-2(3H)-thione

In the structure of the title compound, C(13)H(18)N(2)O(2)S, mol-ecules are linked together by inter-molecular C-H⋯S inter-actions into one-dimensional extended chains along the a axis. The crystal packing is further influenced by weak C-H⋯O inter-actions.

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Amino­silanes derived from 1H-benzimidazole-2(3H)-thione

Two new molecular structures, namely 1,3-bis(trimethylsilyl)-1H-benzimidazole-2(3H)-thione, C13H22N2SSi2, (2), and 1-trimethylsilyl-1H-benzimidazole-2(3H)-thione, C10H14N2SSi, (3), are reported. Both systems were derived from 1H-benzimidazole-2(3H)-thione. Noncovalent C-H···π interactions between the centroid of the benzmidazole system and the SiMe3 groups form helicoidal arrangements in (2). D...

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Chlorido[5-meth­oxy-1H-benzimidazole-2(3H)-thione-κS]bis­(tri­phenyl­phos­phane-κP)copper(I) methanol disolvate

In the title complex, [CuCl(C8H8N2OS)(C18H15P)2]·2CH3OH, the Cu(I) ion is coordinated by one chloride anion, one S atom from the 5-meth-oxy-1H-benzimidazole-2(3H)-thione ligand and two P atoms from two tri-phenyl-phosphine ligands in a distorted tetra-hedral geometry. One of the N-bound H atoms is involved in an intra-molecular N-H⋯Cl hydrogen bond, while another one inter-acts with the solvent...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809008058